Nanocellulose extracted from Paraguayan residual agro-industrial biomass : extraction process, physicochemical and morphological characterization

Correspondence: danielrivaldi@gmail.com.

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Autor principal: Velázquez Figueredo, María Edelira (author)
Otros Autores: Ferreiro Balbuena, Omayra Beatriz (author), Menezes, Diego Batista (author), Corrales Ureña, Yendry (author), Vega Baudrit, José Roberto (author), Rivaldi Chávez, Juan Daniel (author)
Formato: article
Lenguaje:inglés
Publicado: 2022
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Acceso en línea:https://doi.org/10.3390/su141811386
http://hdl.handle.net/20.500.14066/4741
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author Velázquez Figueredo, María Edelira
author2 Ferreiro Balbuena, Omayra Beatriz
Menezes, Diego Batista
Corrales Ureña, Yendry
Vega Baudrit, José Roberto
Rivaldi Chávez, Juan Daniel
author2_role author
author
author
author
author
author_browse Corrales Ureña, Yendry
Ferreiro Balbuena, Omayra Beatriz
Menezes, Diego Batista
Rivaldi Chávez, Juan Daniel
Vega Baudrit, José Roberto
Velázquez Figueredo, María Edelira
author_facet Velázquez Figueredo, María Edelira
Ferreiro Balbuena, Omayra Beatriz
Menezes, Diego Batista
Corrales Ureña, Yendry
Vega Baudrit, José Roberto
Rivaldi Chávez, Juan Daniel
author_role author
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dc.contributor.other.es.fl_str_mv Universidad Americana/INCADE S.A.E
dc.creator.none.fl_str_mv Velázquez Figueredo, María Edelira
Ferreiro Balbuena, Omayra Beatriz
Menezes, Diego Batista
Corrales Ureña, Yendry
Vega Baudrit, José Roberto
Rivaldi Chávez, Juan Daniel
dc.date.accessioned.none.fl_str_mv 2026-01-27T15:20:51Z
dc.date.available.none.fl_str_mv 2026-01-27T15:20:51Z
dc.date.issued.none.fl_str_mv 2022-09-10
dc.format.extent.es.fl_str_mv 15 páginas
dc.identifier.citation.en.fl_str_mv Velázquez, M. E., Ferreiro, O. B., Menezes, D. B., Corrales-Ureña, Y., Vega-Baudrit, J. R., & Rivaldi, J. D. (2022). Nanocellulose Extracted from Paraguayan Residual Agro-Industrial Biomass: Extraction Process, Physicochemical and Morphological Characterization. Sustainability, 14(18), Artículo 11386. https://doi.org/10.3390/su141811386
dc.identifier.doi.es.fl_str_mv 10.3390/su141811386
dc.identifier.issn.es.fl_str_mv 2071-1050
dc.identifier.other.es.fl_str_mv https://doi.org/10.3390/su141811386
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/20.500.14066/4741
dc.language.iso.es.fl_str_mv eng
dc.publisher.es.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.relation.projectCONACYT.es.fl_str_mv PINV18-128
dc.rights.*.fl_str_mv Atribución/Reconocimiento 4.0 Internacional
dc.rights.accessRights.es.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.uri.*.fl_str_mv http://creativecommons.org/licenses/by/4.0/
dc.subject.classification.es.fl_str_mv 6. Producción y tecnología industrial
6.2. Productos industriales y sus procesos de fabricación
dc.subject.ocde.es.fl_str_mv 2. Ingeniería y Tecnología
2.3. Otras ingenierías (tales como ingeniería química, aeronáutica y aeroespacial, mecánica, metalúrgica, de los materiales y sus correspondientes subdivisiones especializadas; productos forestales; ciencias aplicadas, como geodesia, química industrial, etc.; ciencia y tecnología de los alimentos; tecnologías especializadas o áreas interdisciplinares, por ejemplo, análisis de sistemas, metalurgia, minería)
dc.subject.other.es.fl_str_mv Acid hydrolysis
Nanocellulose
Residual biomass
Soybean hulls
Sugarcane bagasse
dc.title.es.fl_str_mv Nanocellulose extracted from Paraguayan residual agro-industrial biomass : extraction process, physicochemical and morphological characterization
dc.type.es.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
description Correspondence: danielrivaldi@gmail.com.
eu_rights_str_mv openAccess
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identifier_str_mv Velázquez, M. E., Ferreiro, O. B., Menezes, D. B., Corrales-Ureña, Y., Vega-Baudrit, J. R., & Rivaldi, J. D. (2022). Nanocellulose Extracted from Paraguayan Residual Agro-Industrial Biomass: Extraction Process, Physicochemical and Morphological Characterization. Sustainability, 14(18), Artículo 11386. https://doi.org/10.3390/su141811386
2071-1050
10.3390/su141811386
language eng
network_acronym_str CONACYT
network_name_str Repositorio Institucional CONACYT
oai_identifier_str oai:repositorio.conacyt.gov.py:20.500.14066/4741
publishDate 2022
publishDateSort 2022
repository.mail.fl_str_mv repositorio.institucional@conacyt.gov.py
repository.name.fl_str_mv Repositorio Institucional CONACYT
repository_id_str
rights_invalid_str_mv Atribución/Reconocimiento 4.0 Internacional
http://creativecommons.org/licenses/by/4.0/
spelling 960cfdbf-c7ca-4313-9c7f-74f971d81a4d60012726000000-0001-8449-1297f61ac03d-d713-4f31-9129-1f36f41951a7600c7601f1a-bc30-4cc4-a9a2-cef32dcd12ca6008261babd-7bdf-41d2-92d8-bf180b5272ed600955600Universidad Americana/INCADE S.A.E2026-01-27T15:20:51Z2026-01-27T15:20:51Z2022-09-10Velázquez, M. E., Ferreiro, O. B., Menezes, D. B., Corrales-Ureña, Y., Vega-Baudrit, J. R., & Rivaldi, J. D. (2022). Nanocellulose Extracted from Paraguayan Residual Agro-Industrial Biomass: Extraction Process, Physicochemical and Morphological Characterization. Sustainability, 14(18), Artículo 11386. https://doi.org/10.3390/su1418113862071-1050https://doi.org/10.3390/su141811386http://hdl.handle.net/20.500.14066/474110.3390/su141811386Correspondence: danielrivaldi@gmail.com.This article belongs to the Special Issue Biomass Treatment Techniques and Sustainable Utilization of Residues.Residual biomasses from agro-industries in Paraguay, including soybean hulls (SBHs) and sugarcane bagasse (SCB), were studied as a source for nanocellulose extraction for the first time. For that purpose, both biomasses were delignified in a semi-pilot stainless-steel reactor, and the cellulose pulp was subjected to a bleaching process with NaClO (2.5%, w/v). The nanocellulose (CNC) was obtained after two-step acid hydrolysis. Firstly, the bleached cellulose was hydrolyzed with HCl (17%, w/w) for two hours at 60 °C to obtain microcrystals by removing most of the amorphous fraction. The celluloses were then treated with H2SO4 (65%, w/w) at 45 °C for 45 min to obtain nanocellulose. Physicochemical and morphological properties were analyzed using attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), atomic force microscopy (AFM), and X-ray diffraction analysis (XRD). The SBHs nanocellulose had a whisker-like form with a 230 ± 42 nm diameter and a 12 ± 2 nm height, and the SCB nanocellulose had a fibril-like form with a 103 ± 30 nm diameter and a height of 6 ± 3 nm. The nanocellulose from SBHs and SCB had good thermal stability as its degradation temperature started at 250 °C. Furthermore, the nanocellulose obtained was negatively charged and formed stable dispersion in water at 0.1 mg/mL concentration and a pH of around 6.5.Consejo Nacional de Ciencia y TecnologíaPrograma Paraguayo para el Desarrollo de la Ciencia y Tecnología. Proyectos de investigación y desarrollo15 páginasengMultidisciplinary Digital Publishing InstituteAtribución/Reconocimiento 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccess© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/).6. Producción y tecnología industrial6.2. Productos industriales y sus procesos de fabricaciónAcid hydrolysisNanocelluloseResidual biomassSoybean hullsSugarcane bagasse2. Ingeniería y Tecnología2.3. Otras ingenierías (tales como ingeniería química, aeronáutica y aeroespacial, mecánica, metalúrgica, de los materiales y sus correspondientes subdivisiones especializadas; productos forestales; ciencias aplicadas, como geodesia, química industrial, etc.; ciencia y tecnología de los alimentos; tecnologías especializadas o áreas interdisciplinares, por ejemplo, análisis de sistemas, metalurgia, minería)Nanocellulose extracted from Paraguayan residual agro-industrial biomass : extraction process, physicochemical and morphological characterizationinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion18SustainabilityPINV18-12814Velázquez Figueredo, María EdeliraFerreiro Balbuena, Omayra BeatrizMenezes, Diego BatistaCorrales Ureña, YendryVega Baudrit, José RobertoRivaldi Chávez, Juan DanielLICENSElicense.txtlicense.txttext/plain; charset=utf-81698http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4741/3/license.txt858b22fda432bd774e469302988c1974MD53ORIGINALNanocellulose extracted from Paraguayan residual agro-industrial biomass: extraction process, physicochemical and morphological characterization.pdfNanocellulose extracted from Paraguayan residual agro-industrial biomass: extraction process, physicochemical and morphological characterization.pdfArtículo científicoapplication/pdf2563835http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4741/1/Nanocellulose%20extracted%20from%20Paraguayan%20residual%20agro-industrial%20biomass%3a%20extraction%20process%2c%20physicochemical%20and%20morphological%20characterization.pdf338228cbc9d02f7023316f5cff057cfcMD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8908http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4741/2/license_rdf0175ea4a2d4caec4bbcc37e300941108MD52THUMBNAILNanocellulose extracted from Paraguayan residual agro-industrial biomass extraction process, physicochemical and morphological characterization.jpgNanocellulose extracted from Paraguayan residual agro-industrial biomass extraction process, physicochemical and morphological characterization.jpgArtículo científicoimage/jpeg545514http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4741/4/Nanocellulose%20extracted%20from%20Paraguayan%20residual%20agro-industrial%20biomass%20extraction%20process%2c%20physicochemical%20and%20morphological%20characterization.jpgd86ad3d51f49773f19a50857bd6574b9MD54TEXTNanocellulose extracted from Paraguayan residual agro-industrial biomass: extraction process, physicochemical and morphological characterization.pdf.txtNanocellulose extracted from Paraguayan residual agro-industrial biomass: extraction process, physicochemical and morphological characterization.pdf.txtExtracted texttext/plain56677http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4741/5/Nanocellulose%20extracted%20from%20Paraguayan%20residual%20agro-industrial%20biomass%3a%20extraction%20process%2c%20physicochemical%20and%20morphological%20characterization.pdf.txt76d9ac871e8bd5d2d58e14219cb52facMD5520.500.14066/4741oai:repositorio.conacyt.gov.py:20.500.14066/47412026-01-28 02:26:26.41Repositorio Institucional CONACYTrepositorio.institucional@conacyt.gov.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
spellingShingle Nanocellulose extracted from Paraguayan residual agro-industrial biomass : extraction process, physicochemical and morphological characterization
Velázquez Figueredo, María Edelira
6. Producción y tecnología industrial
6.2. Productos industriales y sus procesos de fabricación
Acid hydrolysis
Nanocellulose
Residual biomass
Soybean hulls
Sugarcane bagasse
2. Ingeniería y Tecnología
2.3. Otras ingenierías (tales como ingeniería química, aeronáutica y aeroespacial, mecánica, metalúrgica, de los materiales y sus correspondientes subdivisiones especializadas; productos forestales; ciencias aplicadas, como geodesia, química industrial, etc.; ciencia y tecnología de los alimentos; tecnologías especializadas o áreas interdisciplinares, por ejemplo, análisis de sistemas, metalurgia, minería)
status_str publishedVersion
title Nanocellulose extracted from Paraguayan residual agro-industrial biomass : extraction process, physicochemical and morphological characterization
title_full Nanocellulose extracted from Paraguayan residual agro-industrial biomass : extraction process, physicochemical and morphological characterization
title_fullStr Nanocellulose extracted from Paraguayan residual agro-industrial biomass : extraction process, physicochemical and morphological characterization
title_full_unstemmed Nanocellulose extracted from Paraguayan residual agro-industrial biomass : extraction process, physicochemical and morphological characterization
title_short Nanocellulose extracted from Paraguayan residual agro-industrial biomass : extraction process, physicochemical and morphological characterization
title_sort Nanocellulose extracted from Paraguayan residual agro-industrial biomass : extraction process, physicochemical and morphological characterization
topic 6. Producción y tecnología industrial
6.2. Productos industriales y sus procesos de fabricación
Acid hydrolysis
Nanocellulose
Residual biomass
Soybean hulls
Sugarcane bagasse
2. Ingeniería y Tecnología
2.3. Otras ingenierías (tales como ingeniería química, aeronáutica y aeroespacial, mecánica, metalúrgica, de los materiales y sus correspondientes subdivisiones especializadas; productos forestales; ciencias aplicadas, como geodesia, química industrial, etc.; ciencia y tecnología de los alimentos; tecnologías especializadas o áreas interdisciplinares, por ejemplo, análisis de sistemas, metalurgia, minería)
url https://doi.org/10.3390/su141811386
http://hdl.handle.net/20.500.14066/4741