Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco

Corresponding Author: Alex Matos da Silva Costa, Facultad de Ciencias Exactas y Naturales, FACEN–UNA, Campus/UNA, Km 11, C.C. 1039–1804, San Lorenzo, Paraguay. Email: alexmatos@facen.una.py.

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Hovedforfatter: Buzarquis Arias, Deyne Simone Mariel (author)
Andre forfattere: Herrera, Edher Zacarias (author), Colmán Patiño, Christian Fernando (author), Sarubbi Jacks, Yennifer (author), Ríos Díaz, Sergio Daniel (author), Souberlich Barúa, Ricardo Froilan (author), Sánchez González, Christian Javier (author), Matos da Silva Costa, Alex (author)
Format: article
Sprog:engelsk
Udgivet: 2025
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Online adgang:https://doi.org/10.1177/27551857251327408
http://hdl.handle.net/20.500.14066/4665
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author Buzarquis Arias, Deyne Simone Mariel
author2 Herrera, Edher Zacarias
Colmán Patiño, Christian Fernando
Sarubbi Jacks, Yennifer
Ríos Díaz, Sergio Daniel
Souberlich Barúa, Ricardo Froilan
Sánchez González, Christian Javier
Matos da Silva Costa, Alex
author2_role author
author
author
author
author
author
author
author_browse Buzarquis Arias, Deyne Simone Mariel
Colmán Patiño, Christian Fernando
Herrera, Edher Zacarias
Matos da Silva Costa, Alex
Ríos Díaz, Sergio Daniel
Sarubbi Jacks, Yennifer
Souberlich Barúa, Ricardo Froilan
Sánchez González, Christian Javier
author_facet Buzarquis Arias, Deyne Simone Mariel
Herrera, Edher Zacarias
Colmán Patiño, Christian Fernando
Sarubbi Jacks, Yennifer
Ríos Díaz, Sergio Daniel
Souberlich Barúa, Ricardo Froilan
Sánchez González, Christian Javier
Matos da Silva Costa, Alex
author_role author
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http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4665/6/Diagenetic%20processes%20in%20the%20fossilized%20carapace%20of%20Neosclerocalyptus%20sp.%20from%20the%20Paraguayan%20Chaco.pdf.txt
dc.contributor.other.es.fl_str_mv Universidad Nacional de Asunción. Facultad de Ciencias Exactas y Naturales
dc.creator.none.fl_str_mv Buzarquis Arias, Deyne Simone Mariel
Herrera, Edher Zacarias
Colmán Patiño, Christian Fernando
Sarubbi Jacks, Yennifer
Ríos Díaz, Sergio Daniel
Souberlich Barúa, Ricardo Froilan
Sánchez González, Christian Javier
Matos da Silva Costa, Alex
dc.date.accessioned.none.fl_str_mv 2025-10-13T15:04:14Z
dc.date.available.none.fl_str_mv 2025-10-13T15:04:14Z
dc.date.issued.none.fl_str_mv 2025-03-20
dc.format.extent.es.fl_str_mv 12 páginas
dc.identifier.citation.en.fl_str_mv Buzarquis Arias, D. S. M., Herrera, E., Colman, C. F., Sarubbi Jacks, Y., Ríos, S. D., Souberlich, R., Sánchez Gonzales, C. J., & Matos da Silva Costa, A. (2025). Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco. Applied Spectroscopy Practica, 3(1). https://doi.org/10.1177/27551857251327
dc.identifier.doi.es.fl_str_mv 10.1177/27551857251327408
dc.identifier.essn.es.fl_str_mv 2755-1857
dc.identifier.issn.es.fl_str_mv 2755-1857
dc.identifier.other.es.fl_str_mv https://doi.org/10.1177/27551857251327408
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/20.500.14066/4665
dc.language.iso.es.fl_str_mv eng
dc.publisher.es.fl_str_mv Sage
dc.relation.projectCONACYT.es.fl_str_mv PINV15-120
dc.rights.*.fl_str_mv Atribución/Reconocimiento-NoComercial 4.0 Internacional
dc.rights.accessRights.es.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.copyright.es.fl_str_mv © The Author(s) 2025
dc.rights.uri.*.fl_str_mv http://creativecommons.org/licenses/by-nc/4.0/
dc.subject.classification.es.fl_str_mv 10. Cultura, ocio, religión y medios de comunicación
10.4. Servicios culturales
dc.subject.ocde.es.fl_str_mv 6. Humanidades y Artes
6.1. Historia (historia, prehistoria, así como ciencias auxiliares de la historia, tales como la arqueología, la numismática, la paleografía, la genealogía, etc.)
dc.subject.other.es.fl_str_mv Diagenesis process
Fourier transform infrared
FT-IR‌
Hydroxyapatite‌
Neosclerocalyptus sp.
Paleometry
Scanning electron microscopy energy-dispersive spectroscopy
SEM-XRD‌
Spectroscopic analysis
X-ray diffraction
X-ray fluorescence
XRD‌
XRF
dc.title.es.fl_str_mv Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco
dc.type.es.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
description Corresponding Author: Alex Matos da Silva Costa, Facultad de Ciencias Exactas y Naturales, FACEN–UNA, Campus/UNA, Km 11, C.C. 1039–1804, San Lorenzo, Paraguay. Email: alexmatos@facen.una.py.
eu_rights_str_mv openAccess
format article
id CONACYT_57816e8a18e95cc4ea772490b8f78c84
identifier_str_mv Buzarquis Arias, D. S. M., Herrera, E., Colman, C. F., Sarubbi Jacks, Y., Ríos, S. D., Souberlich, R., Sánchez Gonzales, C. J., & Matos da Silva Costa, A. (2025). Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco. Applied Spectroscopy Practica, 3(1). https://doi.org/10.1177/27551857251327
2755-1857
10.1177/27551857251327408
language eng
network_acronym_str CONACYT
network_name_str Repositorio Institucional CONACYT
oai_identifier_str oai:repositorio.conacyt.gov.py:20.500.14066/4665
publishDate 2025
publishDateSort 2025
repository.mail.fl_str_mv repositorio.institucional@conacyt.gov.py
repository.name.fl_str_mv Repositorio Institucional CONACYT
repository_id_str
rights_invalid_str_mv Atribución/Reconocimiento-NoComercial 4.0 Internacional
http://creativecommons.org/licenses/by-nc/4.0/
© The Author(s) 2025
spelling b06ed16f-cff0-4350-9336-d9c48dda9ab06005876003016005c611595-6c01-494b-9b84-483165c9e4046009496001105600f790f761-b8b6-4d09-9f8d-3aecbd79a9626001230600Universidad Nacional de Asunción. Facultad de Ciencias Exactas y Naturales2025-10-13T15:04:14Z2025-10-13T15:04:14Z2025-03-20Buzarquis Arias, D. S. M., Herrera, E., Colman, C. F., Sarubbi Jacks, Y., Ríos, S. D., Souberlich, R., Sánchez Gonzales, C. J., & Matos da Silva Costa, A. (2025). Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco. Applied Spectroscopy Practica, 3(1). https://doi.org/10.1177/275518572513272755-1857https://doi.org/10.1177/27551857251327408http://hdl.handle.net/20.500.14066/466510.1177/275518572513274082755-1857Corresponding Author: Alex Matos da Silva Costa, Facultad de Ciencias Exactas y Naturales, FACEN–UNA, Campus/UNA, Km 11, C.C. 1039–1804, San Lorenzo, Paraguay. Email: alexmatos@facen.una.py.Paleometry is essential in analyzing fossil remains, revealing diagenetic processes through physicochemical characterization techniques that identify crystalline and chemical structures, as well as elemental composition and changes observed via electron microscopy. This study examines the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco, employing these methodologies to understand its diagenetic transformation. Fourier transform infrared (FT-IR) spectra identified phosphate, carbonate, and amide I and II groups. The Gaussian deconvolution model applied to the FT-IR spectra distinguished individual bands within overlapping vibrational modes, providing insights into the presence of stoichiometric and non-stoichiometric calcium phosphates. X-ray diffraction patterns confirmed the crystallinity and apatite nature of the sample, while energy dispersive X-ray fluorescence and scanning electron microscopy energy-dispersive spectroscopy assessed its elemental composition and microstructural characteristics. The results indicated the inclusion of new crystalline phases (quartz) and changes in mineralogy and crystallinity due to environmental interactions. A diagenetic pathway model is proposed, involving initial development, exposure to calcium carbonate-rich water, hydroxyapatite recrystallization, calcite infiltration in pores, and incorporation of new elements. This study enhances the understanding of fossil preservation and environmental influences on diagenetic processes at a regional level as well as being one of the first works on glyptodont carapace characterizations in South America.Consejo Nacional de Ciencia y TecnologíaPrograma Paraguayo para el Desarrollo de la Ciencia y Tecnología. Proyectos de investigación y desarrollo12 páginasengSageAtribución/Reconocimiento-NoComercial 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccess© The Author(s) 202510. Cultura, ocio, religión y medios de comunicación10.4. Servicios culturalesDiagenesis processFourier transform infraredFT-IR‌Hydroxyapatite‌Neosclerocalyptus sp.PaleometryScanning electron microscopy energy-dispersive spectroscopySEM-XRD‌Spectroscopic analysisX-ray diffractionX-ray fluorescenceXRD‌XRF6. Humanidades y Artes6.1. Historia (historia, prehistoria, así como ciencias auxiliares de la historia, tales como la arqueología, la numismática, la paleografía, la genealogía, etc.)Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chacoinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion1Applied Spectroscopy PracticaPINV15-1203Buzarquis Arias, Deyne Simone MarielHerrera, Edher ZacariasColmán Patiño, Christian FernandoSarubbi Jacks, YenniferRíos Díaz, Sergio DanielSouberlich Barúa, Ricardo FroilanSánchez González, Christian JavierMatos da Silva Costa, AlexORIGINALDiagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco.pdfDiagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco.pdfArtículo científicoapplication/pdf4729467http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4665/1/Diagenetic%20processes%20in%20the%20fossilized%20carapace%20of%20Neosclerocalyptus%20sp.%20from%20the%20Paraguayan%20Chaco.pdf33aa45f3a314675d8cd71237f424ab7aMD51sj-docx-1-app-10.1177_27551857251327408.docxsj-docx-1-app-10.1177_27551857251327408.docxMaterial suplementarioapplication/vnd.openxmlformats-officedocument.wordprocessingml.document525186http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4665/5/sj-docx-1-app-10.1177_27551857251327408.docxcef87e41ec415721296489d276c3bc92MD55CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; 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spellingShingle Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco
Buzarquis Arias, Deyne Simone Mariel
10. Cultura, ocio, religión y medios de comunicación
10.4. Servicios culturales
Diagenesis process
Fourier transform infrared
FT-IR‌
Hydroxyapatite‌
Neosclerocalyptus sp.
Paleometry
Scanning electron microscopy energy-dispersive spectroscopy
SEM-XRD‌
Spectroscopic analysis
X-ray diffraction
X-ray fluorescence
XRD‌
XRF
6. Humanidades y Artes
6.1. Historia (historia, prehistoria, así como ciencias auxiliares de la historia, tales como la arqueología, la numismática, la paleografía, la genealogía, etc.)
status_str publishedVersion
title Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco
title_full Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco
title_fullStr Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco
title_full_unstemmed Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco
title_short Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco
title_sort Diagenetic processes in the fossilized carapace of Neosclerocalyptus sp. from the Paraguayan Chaco
topic 10. Cultura, ocio, religión y medios de comunicación
10.4. Servicios culturales
Diagenesis process
Fourier transform infrared
FT-IR‌
Hydroxyapatite‌
Neosclerocalyptus sp.
Paleometry
Scanning electron microscopy energy-dispersive spectroscopy
SEM-XRD‌
Spectroscopic analysis
X-ray diffraction
X-ray fluorescence
XRD‌
XRF
6. Humanidades y Artes
6.1. Historia (historia, prehistoria, así como ciencias auxiliares de la historia, tales como la arqueología, la numismática, la paleografía, la genealogía, etc.)
url https://doi.org/10.1177/27551857251327408
http://hdl.handle.net/20.500.14066/4665