Kinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration

Correspondencia: Magna Monteiro, e-mail: mmonteiro@pol.una.py

محفوظ في:
التفاصيل البيبلوغرافية
المؤلف الرئيسي: Caballero González, Norma Beatriz (author)
مؤلفون آخرون: Casanova Ozuna, Pablo Javier (author), Monteiro Schaerer, Magna María (author)
التنسيق: article
اللغة:الإنجليزية
منشور في: 2019
الموضوعات:
الوصول للمادة أونلاين:http://dx.doi.org/10.1590/1980-5373-MR-2018-0859
http://hdl.handle.net/20.500.14066/4528
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author Caballero González, Norma Beatriz
author2 Casanova Ozuna, Pablo Javier
Monteiro Schaerer, Magna María
author2_role author
author
author_browse Caballero González, Norma Beatriz
Casanova Ozuna, Pablo Javier
Monteiro Schaerer, Magna María
author_facet Caballero González, Norma Beatriz
Casanova Ozuna, Pablo Javier
Monteiro Schaerer, Magna María
author_role author
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dc.contributor.other.es.fl_str_mv Universidad Nacional de Asunción. Facultad Politécnica
dc.creator.none.fl_str_mv Caballero González, Norma Beatriz
Casanova Ozuna, Pablo Javier
Monteiro Schaerer, Magna María
dc.date.accessioned.none.fl_str_mv 2025-02-11T13:20:32Z
dc.date.available.none.fl_str_mv 2025-02-11T13:20:32Z
dc.date.issued.none.fl_str_mv 2019-09-30
dc.format.extent.es.fl_str_mv 7 páginas
dc.identifier.citation.en.fl_str_mv Caballero, N., Casanova Ozuna, P., & Monteiro, M. (2019). Kinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration. Materials Research Ibero-american Journal of Materials, 22, Artículo e20180859. http://dx.doi.org/10.1590/1980-5373-MR-2018-0859
dc.identifier.doi.es.fl_str_mv 10.1590/1980-5373-MR-2018-0859
dc.identifier.essn.es.fl_str_mv 1980-5373
dc.identifier.issn.es.fl_str_mv 1516-1439
dc.identifier.other.es.fl_str_mv http://dx.doi.org/10.1590/1980-5373-MR-2018-0859
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/20.500.14066/4528
dc.language.iso.es.fl_str_mv eng
dc.publisher.es.fl_str_mv Associação Brasileira de Metalurgia e Materiais
dc.publisher.pt.fl_str_mv Associação Brasileira de Cerâmica
Associação Brasileira de Polímeros
dc.relation.projectCONACYT.es.fl_str_mv 14-INV-267
dc.rights.*.fl_str_mv Atribución 4.0 Internacional
dc.rights.accessRights.es.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.copyright.es.fl_str_mv © 2019 Caballero et al.
dc.rights.uri.*.fl_str_mv http://creativecommons.org/licenses/by/4.0/
dc.subject.classification.es.fl_str_mv 2. Medio ambiente
2.7. Protección del agua
dc.subject.other.es.fl_str_mv Diffusion models
High lead concentration
Load zero-point
dc.title.es.fl_str_mv Kinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration
dc.type.es.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
description Correspondencia: Magna Monteiro, e-mail: mmonteiro@pol.una.py
eu_rights_str_mv openAccess
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identifier_str_mv Caballero, N., Casanova Ozuna, P., & Monteiro, M. (2019). Kinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration. Materials Research Ibero-american Journal of Materials, 22, Artículo e20180859. http://dx.doi.org/10.1590/1980-5373-MR-2018-0859
1516-1439
10.1590/1980-5373-MR-2018-0859
1980-5373
language eng
network_acronym_str CONACYT
network_name_str Repositorio Institucional CONACYT
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publishDate 2019
publishDateSort 2019
repository.mail.fl_str_mv repositorio.institucional@conacyt.gov.py
repository.name.fl_str_mv Repositorio Institucional CONACYT
repository_id_str
rights_invalid_str_mv Atribución 4.0 Internacional
http://creativecommons.org/licenses/by/4.0/
© 2019 Caballero et al.
spelling 208600df385f62-bcb8-42c7-94b2-2ab738dcc25f6007766000000-0002-5078-7214Universidad Nacional de Asunción. Facultad Politécnica2025-02-11T13:20:32Z2025-02-11T13:20:32Z2019-09-30Caballero, N., Casanova Ozuna, P., & Monteiro, M. (2019). Kinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration. Materials Research Ibero-american Journal of Materials, 22, Artículo e20180859. http://dx.doi.org/10.1590/1980-5373-MR-2018-08591516-1439http://dx.doi.org/10.1590/1980-5373-MR-2018-0859http://hdl.handle.net/20.500.14066/452810.1590/1980-5373-MR-2018-08591980-5373Correspondencia: Magna Monteiro, e-mail: mmonteiro@pol.una.pyThe aim of this work was to study of the kinetic of Pb(II) sorption, in high lead concentration aqueous solution, by the natural hydroxyapatite (HA) and to verify whether there is a different behavior between natural and synthetic HA under different lead concentrations. Batch experiments were carried out using solutions with high lead concentration, with the objective to evaluate the effect of contact time, HA dosage and initial metal concentration on lead removal. Kinetic data were analyzed by pseudo-first and pseudo-second order models. The sorption data was then correlated with the Langmuir and Freundlich isotherm models. The PZC obtained was slightly different than those reported by other authors, who evaluated the process under low concentrations and synthetic HA as adsorbent. It was possible to identify the optimum relation between Pb(II) concentrations and mass of HA for efficiency of approximately 100% at optimum contact time. Although the results show a certain instability during the removal of lead when the concentration is much higher, the process can be considered effective. Liquid samples were analyzed by atomic absorption spectroscopy and solid samples were by X-ray diffraction and Fourier transform infrared spectroscopy.Consejo Nacional de Ciencia y TecnologíaPrograma Paraguayo para el Desarrollo de la Ciencia y Tecnología. Proyectos de investigación y desarrollo7 páginasengAssociação Brasileira de Metalurgia e MateriaisAssociação Brasileira de CerâmicaAssociação Brasileira de PolímerosAtribución 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccess© 2019 Caballero et al.2. Medio ambiente2.7. Protección del aguaDiffusion modelsHigh lead concentrationLoad zero-pointKinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentrationinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionMaterials Research Ibero-american Journal of Materials14-INV-26722Caballero González, Norma BeatrizCasanova Ozuna, Pablo JavierMonteiro Schaerer, Magna MaríaORIGINALKinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration.pdfKinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration.pdfArtículo científicoapplication/pdf779552http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4528/1/Kinetic%20analysis%20of%20lead%20removal%20by%20natural%20hydroxyapatite%20from%20aqueous%20solution%20in%20high%20concentration.pdfceeaf9259688719de528de89a97060b5MD51THUMBNAILKinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration.jpgKinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration.jpgVista de primera página de artículo científicoimage/jpeg1004653http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4528/4/Kinetic%20analysis%20of%20lead%20removal%20by%20natural%20hydroxyapatite%20from%20aqueous%20solution%20in%20high%20concentration.jpgd703dd183a11bc154f7d3219b874c02dMD54CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8908http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4528/2/license_rdf0175ea4a2d4caec4bbcc37e300941108MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81698http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4528/3/license.txt858b22fda432bd774e469302988c1974MD53TEXTKinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration.pdf.txtKinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration.pdf.txtExtracted texttext/plain26541http://repositorio.conacyt.gov.py/bitstream/20.500.14066/4528/5/Kinetic%20analysis%20of%20lead%20removal%20by%20natural%20hydroxyapatite%20from%20aqueous%20solution%20in%20high%20concentration.pdf.txtf043b36236f550a89f3e1c5d4af56345MD5520.500.14066/4528oai:repositorio.conacyt.gov.py:20.500.14066/45282026-02-12 19:30:39.924Repositorio Institucional CONACYTrepositorio.institucional@conacyt.gov.pyQWwgYWNlcHRhciBlc3RhIGxpY2VuY2lhLCB1c3RlZCBjb21vIGF1dG9yIHkgcHJvcGlldGFyaW8gZGUgbG9zIGRlcmVjaG9zIGRlIHByb3BpZWRhZCBpbnRlbGVjdHVhbCBkZSBzdSBvYnJhIG90b3JnYSBhbCBSZXBvc2l0b3JpbyBJbnN0aXR1Y2lvbmFsIENPTkFDWVQgZWwgZGVyZWNobyBubyBleGNsdXNpdm8gZGUgcmVwcm9kdWNjacOzbiB5IGRpc3RyaWJ1Y2nDs24gZGUgc3Ugb2JyYSBlbiBjdWFscXVpZXIgZm9ybWF0byB5IG1lZGlvLgoKQWNlcHRhIHF1ZSwgc2luIG1vZGlmaWNhciBlbCBjb250ZW5pZG8sIHNlIHB1ZWRhIGNvbnZlcnRpciBzdSBvYnJhIGEgb3RybyBmb3JtYXRvIGNvbiBmaW5lcyBkZSBwcmVzZXJ2YWNpw7NuLiBBc8OtIG1pc21vLCBhY2VwdGEgcXVlIHNlIHB1ZWRhIGNvbnNlcnZhciBtw6FzIGRlIHVuYSBjb3BpYSBwb3IgbW90aXZvcyBkZSBzZWd1cmlkYWQgeSBwcmVzZXJ2YWNpw7NuLgoKVXN0ZWQgZGVjbGFyYSBxdWUgZWwgdHJhYmFqbyBwcmVzZW50YWRvIGVzIG9yaWdpbmFsIHkgcXVlIGN1ZW50YSBjb24gbGEgcG90ZXN0YWQgcGFyYSBvdG9yZ2FyIGxvcyBkZXJlY2hvcyBkZXRhbGxhZG9zIGVuIGVzdGEgbGljZW5jaWEuIFRhbWJpw6luIGRlY2xhcmEgcXVlIHN1IG9icmEgbm8gaW5mcmluZ2UgbG8gZXN0YWJsZWNpZG8gZW4gbGEgdmlnZW50ZSBsZWdpc2xhY2nDs24gc29icmUgcHJvcGllZGFkIGludGVsZWN0dWFsLgoKU2kgbGEgb2JyYSBjb250aWVuZSBtYXRlcmlhbCBwYXJhIGVsIGN1YWwgbm8gdGllbmUgZGVyZWNob3MgZGUgYXV0b3IsIHVzdGVkIGRlY2xhcmEgcXVlIGhhIG9idGVuaWRvIGxvcyBwZXJtaXNvcyBuZWNlc2FyaW9zIGRlbCBwcm9waWV0YXJpbyBwYXJhIG90b3JnYXIgYWwgUmVwb3NpdG9yaW8gSW5zdGl0dWNpb25hbCBDT05BQ1lUIGxvcyBkZXJlY2hvcyByZXF1ZXJpZG9zIHBvciBlc3RhIGxpY2VuY2lhLCB5IHF1ZSBkaWNobyBtYXRlcmlhbCBkZSBwcm9waWVkYWQgZGUgdGVyY2Vyb3MgZXN0w6EgY2xhcmFtZW50ZSBpZGVudGlmaWNhZG8geSByZWNvbm9jaWRvIGRlbnRybyBkZWwgY29udGVuaWRvIGRlIGxhIG9icmEuCgpTaSBsYSBvYnJhIHF1ZSBkZXBvc2l0YSBoYSBzaWRvIHBhdHJvY2luYWRhIG8gZmluYW5jaWFkYSBwb3IgdW5hIG9yZ2FuaXphY2nDs24sIHVzdGVkIGRlY2xhcmEgcXVlIGhhIGN1bXBsaWRvIGNvbiBsYXMgb2JsaWdhY2lvbmVzIHJlcXVlcmlkYXMgcG9yIHRhbCBhY3VlcmRvLgoKU2kgZWwgZG9jdW1lbnRvIHNlIGJhc2EgZW4gdW5hIG9icmEgcXVlIGhhIHNpZG8gcGF0cm9jaW5hZGEgbyBhcG95YWRhIHBvciB1bmEgYWdlbmNpYSB1IG9yZ2FuaXphY2nDs24sIHNlIHByZXN1cG9uZSBxdWUgc2UgaGEgY3VtcGxpZG8gY29uIGN1YWxxdWllciBkZXJlY2hvIGRlIHJldmlzacOzbiB1IG90cmFzIG9ibGlnYWNpb25lcyByZXF1ZXJpZGFzIHBvciBlc3RlIGNvbnRyYXRvIG8gYWN1ZXJkby4KCkVsIFJlcG9zaXRvcmlvIEluc3RpdHVjaW9uYWwgQ09OQUNZVCBpZGVudGlmaWNhcsOhIGNsYXJhbWVudGUgc3UvcyBub21icmUvcyBjb21vIGVsL2xvcyBhdXRvci9lcyBvIHByb3BpZXRhcmlvL3MgZGUgbG9zIGRlcmVjaG9zIGRlbCBkb2N1bWVudG8sIHkgbm8gaGFyw6EgbmluZ3VuYSBhbHRlcmFjacOzbiBkZSBzdSBkb2N1bWVudG8gZGlmZXJlbnRlIGEgbGFzIHBlcm1pdGlkYXMgZW4gZXN0YSBsaWNlbmNpYS4K
spellingShingle Kinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration
Caballero González, Norma Beatriz
2. Medio ambiente
2.7. Protección del agua
Diffusion models
High lead concentration
Load zero-point
status_str publishedVersion
title Kinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration
title_full Kinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration
title_fullStr Kinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration
title_full_unstemmed Kinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration
title_short Kinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration
title_sort Kinetic analysis of lead removal by natural hydroxyapatite from aqueous solution in high concentration
topic 2. Medio ambiente
2.7. Protección del agua
Diffusion models
High lead concentration
Load zero-point
url http://dx.doi.org/10.1590/1980-5373-MR-2018-0859
http://hdl.handle.net/20.500.14066/4528